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敏化的1Cr18Ni9Ti在炼油厂含连多硫酸水样中的应力腐蚀

SCC OF SENSITIZED 1Cr18Ni9Ti STAINLESS STEEL IN H2SxO6 SOLUTION IN REFINERY

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【作者】 段学章许素珍李铁藩

【Author】 Duan Xuezhang Xu Suzhen and Li Tiefan (Institute of Corrosion and Protection of Metals,Academia Sinica)

【机构】 中国科学院金属腐蚀与防护研究所中国科学院金属腐蚀与防护研究所

【摘要】 <正> 连多硫酸(HzSxO6,x=2,3,4,5)容易引起敏化的奥氏体不锈钢发生应力腐蚀开裂。前人测定不锈钢在Samens溶液中的阳极极化曲线,或用U型试样进行应力蚀研究。本工作采用炼油厂的现场水样,测定敏化的1Cr18Ni9Ti不锈钢的电化学行为和应力腐蚀敏感性。

【Abstract】 Stress Corrosion Cracking(SCC)susceptibility of sensitized 1 Cr18Ni9Ti austenitic steel was investigated by measuring potgntiody- namie polarization curves(sean rates:10 mV/min and 20 mV/s)and using the slow strain rate test(SSRT)in the polythionic acid solution formed in the petroleum refinery. The results showed that there was a critical potential range between +60 and +1200 mV(SCE)in H2SxO6 solution in refinery for stress corrosion cracking of sensitized 1 Cr18Ni9Ti stainless steel to occur. The metallographic studies of the fractured surface by SEM revealed intergranular and quasi-cleavage fracture in the critical potential zone.

【基金】 中国科学院腐蚀科学开放实验室资助
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society for Corrosion and Protection , 编辑部邮箱 ,1990年03期
  • 【被引频次】3
  • 【下载频次】42
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