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醇酸树脂的分子量分布的研究

Distribution of Molecular Weight of Polyesters by GPC

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【作者】 蔡春爱; 刘风歧; 汤心颐; 金春山;

【Author】 Cai Chunai, Liu Fengqi and Tang Xinyi(Department of Chemistry, Jilin University) Jin Chunshan(Changchun Institute of Applied Chemisty, Academic Sinica)

【机构】 吉林大学化学系; 长春应用化学研究所;

【摘要】 用凝胶色谱(简称GPC)研究了醇酸树脂的分子量分布。结果表明,平均分子量随反应时间的增加而增大,其分布是从对称分布逐渐变成不对称分布。

【Abstract】 The molecular weight of polyesters was measured with GPC,VPO and intrinsic viscosity. In this work with the aid of theoretical treatment, the experimental results were translated into the calibration curve.When this curve was combined with the universal calibration curve, most promising parameters,e.g. K,α, and [η] were obtained. The results showed the molecular weight increases with the reaction time and the content of water decreases in ester bodies.

  • 【文献出处】 吉林大学自然科学学报 ,Journal of Jilin University , 编辑部邮箱 ,1989年02期
  • 【下载频次】73
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