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置换萃取色谱法分离富集矿石中微量镓

Replacement Extraction Chromatographic Separation and Preconcentration of Trace Gallium in Ores

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【作者】 范必威; 曾宪明; 周国生;

【Author】 Fan Biwei Zeng Xianming Zhou Quosheng(Department of Applied Chemistry, Chengdu College of Geology)

【机构】 成都地质学院应用化学系; 成都地质学院; 成都地质学院 83届毕业生; 83届毕业生;

【摘要】 本文提出以二乙基二硫代胺基甲酸铋Bi(DDC)8为固定相,硅胶为载体,以HAc—NaAc(pH=3)缓冲液为上柱液并淋洗杂质离子,用0.5M的盐酸溶液洗脱镓,以罗丹明B分光光度法测定。

【Abstract】 A highly selective rapid separation procedure for galliun has been developed. It is based on the extraction chromatography of gallium from HAc-NaAc(pH=3) solution using bismuth dithyldithiocarbamate as replacement extractant. 0.5M HCl is chosen as eluent for the elution of impuritions. The separation has been applied to the determination of trace gallium in ores by spectrophotometry.

  • 【文献出处】 冶金分析 ,Metallurgical Analysis , 编辑部邮箱 ,1988年04期
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