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差热分析(DTA)法研究五水硫酸铜的失水过程

STUDIES ON ANHYDRATION OF CuSO4·5H2O USING DIFFERENTIAL THERMAL ANALYSIS

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【作者】 潘云祥; 冯增媛; 吴衍荪;

【Author】 Pan Yunxiang Feng Zengyuan Wu Yansun ( Department of Chemistry, Tianjin Normal University )

【机构】 天津师范大学化学系; 天津师范大学化学系;

【摘要】 <正> 关于五水硫酸铜的失水过程有不同的说法。归纳起来,主要有以下几种:1.五水硫酸铜的失水过程分三步进行,即

【Abstract】 At present time, there are several ways to explain the anhydration of copper(Ⅱ) sulphate pentahydrate. Most of chemists consider that the anhydration is undertaken via three steps, others think it would be done through two steps.The present studies on the anhydration of CuSO4·5H2O using DTA, show that under thermal eqilibrium condition anhydration is finished via four steps. Water molecules are removed from CuSO4·5H2O in the order of 2,1,1,1. The temperature range closing thermal eqilibrium for each step of anhydration depends on the experimental conditions(such as heating rate, size of grain, etc.), and is present in this work.

【关键词】 差热分析; 硫酸铜;
【Key words】 DTA copper sulphate;
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,1988年03期
  • 【被引频次】16
  • 【下载频次】3762
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