【摘要】 本文提出了强偶合系统的弱偶合方法处理。利用么正变换,把强偶合系统的哈密顿变成弱偶合系统哈密顿的形式,射频脉冲也作相同的变换,这样强偶合系统的多脉冲实验就能在弱偶合空间{Φ}中计算。以AB体系的COSY和2D-J谱为例作了计算和讨论。更多还原

【Abstract】 A method for describing strong coupling systems by weak coupling system method is suggested. Hamiltonian of strong coupling system was transfered into the form of weak coupling system by using unitary transformation, the same transformation was also applied to rf pulses. The multiple pulse experiments for strong coupling system were calculated in weak coupling space {φ}. As an example, COSY and 2D-J spectra in AB system were calculated.更多还原