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稀土钇(Ⅲ)和某些二酰异羟肟酸配合物的研究
Study on Complexes of Rare-Earth Yttium(Ⅲ) and Some Dioyihydroxamic Acids
【摘要】 本文介绍了在酸性介质中,稀土钇(Ⅲ)分别与邻苯二酰异羟肟酸(O-PhHA)、乙二酰异羟肟酸(OXHA)及己二酰异羟肟酸(AdHA)反应生成配合物的方法。对配合物进行红外光谱和热重分析法研究,并用PH滴定法求出它们的稳定常数K稳依次为1.90×1021、4.17×1021及5.15×1031。
【Abstract】 This paper introduces a method of forming the complexes by reactingRare-earth yttrium(Ⅲ) with o-phthaloylhydroxamic acid (O-PhHA),oxalohydroxamic acid (OxHA) and Adlpylhydroxamic acid (AdHA)inslightly acid medium respectively. The three new complexes have been stu-died by means of infrared spectra and thermal analysis. Furthermore, theirstability constants K have been found to be 1.90×1021,4.17×1021and 5.75×1031 respectively by PH titrimetric method.
- 【文献出处】 南昌大学学报(理科版) ,Journal of Nanchang University(Natural Science) , 编辑部邮箱 ,1988年01期
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