【摘要】 测定了在不同硫酸盐水合物催化下取代醇与乙酸反应的速率常数,给出了包括取代基极性和催化剂效应两项贡献的催化线性自由能方程:lg[k_R（M）/K_0（M）]=^M′σ^*+y_m更多还原

【Abstract】 Kinetic mensurement has been carried in the esterification reaction of a series of substituted alcohols with acetic acid in present of hydrated sulphate salts. The system can be described with Taft equation lg [k/k₀] = ρ^*σ^*. The following Linear Free Energy Equation is presented:lg(k_R（M） /k_0（M）= ρ^M’σ^*Where k_R（M） is the rate constant of the esterification reaction of substituted alcohol catalyzed by hydrated sulphate salts of M metal,k_0（M） is the rate constant of ethanol with acetic acid catalyzed by the salts of M metal. ρ^M’ includes both the polar effects of substituents and the effects of catalyst.更多还原