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N-对硝基苯基甲基丙烯酰胺与甲基丙烯酸甲酯共聚合的研究
A STUDY ON COPOLYMERIZATION OF METHYL METHACRYLATE AND N-p-NITROPHENYLMETH- ACRYLAMIDE
【摘要】 <正> 关于N-芳基取代甲基丙烯酰胺与甲基丙烯酸甲酯共聚合,前曾报道了N-PhMA与MMA,N-p-BrPhMA与MMA及N-P-TMA与MMA等共聚体系。本文研究了N-对硝基苯基甲基丙烯酰胺(N-p-NPhMA)与甲基丙烯酸甲酯(MMA)的共聚反应,
【Abstract】 The N-p-nitrophenylmethacrylamide (N-pNPhMA) was synthesized by the interaction of p-nhrophenylamine with methacryloyl chloride in the presence of triethylamine. This monomer was characterized by IR. and 1H NMR method.The N-p-NPhMA-co-MMA bulk copolymers have been prepared and characterized by IR and 1H NMR.The reactivity ratios of copolymerization of the N-p-NPhMA with MMA were obtained (r1 = 5.05±0.02 for MMA, r, = 0.29±0.02 for N-p-NPhMA) by using of a ’H NMR method.The N-p-NPhMA-co-MMA bulk copolymers are golden and transparent.
【关键词】 N-对硝基苯基甲基丙烯酰胺;
共聚合;
竞聚率;
~1H NMR;
【Key words】 N-p-Nitrophenylmethacrylamide; Copolymers; Ratios of Reaction; 1H NMR;
【Key words】 N-p-Nitrophenylmethacrylamide; Copolymers; Ratios of Reaction; 1H NMR;
- 【文献出处】 高分子学报 ,Acta Polymerica Sinica , 编辑部邮箱 ,1988年05期
- 【被引频次】1
- 【下载频次】51