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二(1,8萘啶氮氧化物)合硝酸钍(Ⅳ)和铀酰(Ⅱ)配合物的合成及其性质
SYNTHESIS AND CHARACTERIZATION OF 1,8-NAPHTHYRIDINE-N-OXIDE COMPLEXES OF THORIUM AND URANYL NITRATES
【摘要】 制得二(1,8-萘啶氮氧化物)合硝酸钍和铀酰配合物,元素分析确定其组成为Th(C3H6N2O)2(NO3)4和UO2(C3H6N2O)2(NO3)2。通过红外光谱、荧光光谱、摩尔电导、差热热重分析等方法,研究了配合物的性质。
【Abstract】 The 1,8-naphthyridine-N-oxide complexes of thorium and uranyl nitrates having composition Th(C8H6N2O)2(NO3)4 and UOa(C3H6NzO)2(NOa)2 have been synthesized using methanol as reaction medium and triethyl orthofor-mate as dehydrant. The new complexes have been characterized by elemental analysis, infrared spectra, fluorescence spectra, molar conductance, differential thermal analysis (DTA) and thermogravimetry (TG).
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,1986年03期
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