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STRUCTURE OF Cu(Ⅱ)-(B15, C-5) COMPLEX

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【作者】 游效曾； 李重德； 杨星水； 李邨； 王定能； 黄锦顺；

【Author】 YOU XIAOZENG LI ZHONGDE YANG XINGSHUI LI CUN WANG DINGNENG (Coordination Chemistry Institute, Nanjing University) HUANG JINSHUN (Fujian Institute of Research on The Structure of Matter, Aoademia Sinica, Fuzhou)

【机构】 Coordination Chemistry Institute； Nanjing University； Fujian Institute of Research on The Structure of Matter； Aoademia Sinica； Fuzhou；

【摘要】 <正> There have been many works on alkali and earth alkali-metal crown complexes. Due to the large solvation energy of metal ions, coupled with the inherent poor basic character of oxygen in —CH2—O—CH2— unit, only very little is known about transition metal complexes of crown ether. From the viewpoint of the model system for Cu（Ⅱ） site in metalloproteins, the study of copper crown complexes has drawn much interest. The conclusion that there was no reaction between the Cu（Ⅱ） and （B15-C-5） in methanol-H2O solvent was drawn from the study of thermo-effeet. By using UB-Vis

【关键词】 alkali； methanol； crown； viewpoint； complexes； B15； C-5； COMPLEX； inherent； conclusion；
  • 【文献出处】 A Monthly Journal of Science ,科学通报(英文版) , 编辑部邮箱 ,1985年01期
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