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微量添加物P2O5对平板玻璃某些相变的影响

THE EFFECT OF MINOR ADDITION OF P2O5 ON SOME PHASE TRANSFORMATION OF PLATE GLASS

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【作者】 江仲华; 周志朝; 汤荣昌; 丁子上;

【Author】 Jiang Zhonghua Zhou Zhichao Tang Rongchang Ding Zishang(Department of Materials Science and Engineering, Zhejiang University)

【机构】 浙江大学材料科学及工程学系; 浙江大学材料科学及工程学系;

【摘要】 在初晶相为鳞石英的平板玻璃中加入千分之几的P2O5后对析晶性能的影响与初晶相为硅灰石的平板玻璃是不同的。但它们仍遵循多元相平衡关系。透射电镜观察和电阻率测量表明,加入微量P2O5能促进平板玻璃的分相。XPS测量结果进一步揭示了由于加入微量P2O5所引起平板玻璃结构上的一些变化。

【Abstract】 The effect of addition of P2O5 in a few thousandths on the devitrification behavior of plate glass with primary phase of tridymite is different from that with primary phase of wollastonite. Such effect still follows phase equilibrium relationship of multicomponents. Based on TEM observation and measurement of electrical resistivity, it indicates that phase separation of plate glass may be improved by adding a minor amount of p2O5·Through XPS measurement, it is shown further that such addition will cause a certain change in structure of plate glass.

【基金】 中国科学院科学基金
  • 【文献出处】 硅酸盐学报 ,Journal of The Chinese Ceramic Society , 编辑部邮箱 ,1985年02期
  • 【下载频次】27
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