【摘要】 考察了工业萘中脱除杂原子氮的动力学,其反应速度可用Langmuir-Hinshel-wood 模型表示,其碱氮的脱除为表观一级反应。在经简化整理后的动力学方程C=C_?e^-kt中,在290℃、320℃、350℃下,k 值分别为0.5398,0.7958和1.2411。脱氮反应的表观活化能为11.2 kcal/mol。本文还探讨了工业萘加氢精制的主要付反应萘加氢生成四氢萘的过程。萘加氢生成四氢萘是可逆一级反应,其动力学方程为:x=x_e(1-e^-kt)。在动力学方程中,290℃、320℃、350℃下的平衡浓度和k 值分别依次为0.9534、0.1659;0.8359、0.5291;0.5868、1.8631。正向反应的活化能为22.5 kcal/mol。更多还原

【Abstract】 The kinetics of the removal of cyclic nitrogen compound in indus-trial naphthalene was investigated.Its kinetics can be related by Langmuir-Hinshelwood models,and is a pseudo-first order reaction.The k for 290℃,320℃ and 350℃ in the simplified equation C=C₀^-ktare 0.5398,0.7958and 1.4211 respectively.Apparent activation energy is 11.2kcal/mol.The hydrogenation of naphthalene to tetrahydronaphthalene is themain side reaction of hydrorefining of industrial naphthalene.It is areversible first order reaction,the k for 290℃,320℃ aud 350℃ in thekinetic equation x=x_e(1-e^-kt)are 0.1659,0.5291 and 1.8631 respecti-vely with x_e equal 0.9534,0.8359 and 0.5868 respectively.The activationenergy is 22.5 kcal/mol.更多还原