【摘要】 <正> 近年来,过渡金属配位化合物的研究发展很快。为了配合这方面工作的开展,红外光谱方法是一种重要而简便的手段。但是,振动光谱的频率随着不同中心离子及各种配位基的组成不同而变异,因而在鉴别这些配位化合物时产生困难。本文试图从图论的角度,对具有反馈键的一些典型配位化合物的振动光谱进行初步介绍和分更多还原

【Abstract】 In this article the application of graph theory to the vibrational spectra of the coordination compounds has been described.According to the view of graph theory the coordination compound looks like a graph.It consists of the vertexes and the edges,there are the flows through the edge from one vertcx to another vertex.The effects of the central ion and the different ligands on frequencies of the infrared spectra of the coordination compounds are discussed.From the above analysis it can be seen that the change of frequencies of vibrational spectra for the coordination compounds can be simply provided,if the graph theory is applied.更多还原