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关于相图的复盖原理

THE "COVER PRINCIPLE" OF PHASE DIAGRAM

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【作者】 单子安;

【Author】 Shan Zi-an

【机构】 西南师范学院化学系;

【摘要】 物质的基本存在形态是单相态,各单相态可以看作是决定物质相态各条件的函数。由相函数的几何表象得出:热力学相平衡图实质上是相函数的投影图。利用“复盖原理”对单相区、复相区和相不定区的形成及判读作了分析。试图通过回答“什么是相图”这一基本问题,来建立简明统一的相图理论。

【Abstract】 The fundamental state exist of a substance in the state in a single phase, which can be treated as a function, may be called "phase function." From the geometrical representation of the phase function, it is pointed out that the thermodynamic phase equilibrium diagram is in essence a projection diagram of phase function. In this article, I put forward a "cover principle" and make an analysis about the formation and also the criterion of different regions in phase diagram,such as the single-phase region, the two-phase region and the region in which the phase is uncertain. Here the intention is to build up a concise and united theory of phase diagram through the answer to the fundamental problem "what is phase diagram.

  • 【文献出处】 西南师范学院学报(自然科学版) , 编辑部邮箱 ,1983年01期
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