The objective of this study was to investigate the disciplinarian of infection about the solution of surfactants to the VOCs of toluene in air-liquid interface's transfer. And then deduced the formula of the relationship between the concentrations of surfactants's solution, temperatures and the Henry's constants. For the research of VOCs's transfer and translate in the environment, and for the wipe of VOCs in the remediatior of soil and groundwater provide the theory and data sustain. We mostly studied sing...