<正>In the presence of diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate(DHP) and a catalytic amount of potassium iodide,severalα-halo ketones were easily reduced to the corresponding ketones in acetone media.The procedure presented here showed several merits such as short reaction time,practical experimental and isolated procedure,and excellent yields of products.
【英文摘要】
In the presence of diethyl 1,4-dihydro-2,6-dimethylpyridine-3,5-dicarboxylate(DHP) and a catalytic amount of potassium iodide,severalα-halo ketones were easily reduced to the corresponding ketones in acetone media.The procedure presented here showed several merits such as short reaction time,practical experimental and isolated procedure,and excellent yields of products.
【基金】
the Guangdong Natural Science Foundation(No.8151063201000016);
the National Natural Science Foundation of China(No.20672046) for financial support
【更新日期】
2010-09-25
【分类号】
O643.32
【正文快照】
The redueed form of nieotinamide adenine dinueleotide eoenzyme【NAD(P)H]Plays a erueial role in biologieal systems as a source oftwoelectronsandaProton[l]·OverthePastyears,anumberofl,4一dihydroPyridinederivatives,including the Hantzseh ester,diethyll