The Ti-Fe alloy compound was prepared by FFC in the molten salts at 700℃.The preformed cathode feed was fabricated with the slurry of mixing TiO_2 and Fe power.The graphite rod was used as the anode in the corundum crucible.At cell voltage of 3.4 V,electro-deoxidation was carried out.With different stoichiometric ratios of Fe and TiO_2 powder,different currency-time plots were gotten,which showed that the more Fe addition,the quicker the reaction speed is during the first 7 hours deoxidation.