The dispersion of V2O5 onto hexagonal mesoporous silicas was investigated by means of X-ray diffraction(XRD).The mesoporous silicas were impregnated by vion solution and calcined in air at 400 °C,the investigation indicated not only vanadium in samples prepared by impregnation method was incorporated into the famework of mesoporous silicas,but also some dispersed spontaneously onto the surface of mesoporous silicas,and formed a monolayer if total amount of V2O5 increased.