RHEOLOGICAL BEHAVIOR OF POLYMER MELTS (Ⅱ) MULTIPLE ENTANGLEMENT MODEL FOR PREDICTING THE DEPENDENCE OF VISCOELASTIC BEHAVIOR ON DEFORMATION STATE AND PRIMARY MOLECULAR WEIGHTS AND THEIR DISTRIBUTION   推荐 CAJ下载
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【英文篇名】
RHEOLOGICAL BEHAVIOR OF POLYMER MELTS(Ⅱ) MULTIPLE ENTANGLEMENT MODEL FOR PREDICTING THE DEPENDENCE OF VISCOELASTIC BEHAVIOR ON DEFORMATION STATE AND PRIMARY MOLECULAR WEIGHTS AND THEIR DISTRIBUTION
<正> In accordance with the memory function of Gaussian chain constraints in entangled polymermelts a set of material functions related to a certaintest floware formulated from the O-W-Ftype constitutive equation by the appropriate selection of the Cauchy-Green and Finger tensors.Thedependences of these material functions on the strain rate and the dependences of the linearviscoelastic functions on the primary molecular weight distribution and the entanglement sites sequencedistribution on polymer chain are ...
【英文摘要】
In accordance with the memory function of Gaussian chain constraints in entangled polymer melts a set of material functions related to a certain test flow are formulated from the O-W-F type constitutive equation by the appropriate selection of the Cauchy-Green and Finger tensors. The dependences of these material functions on the strain rate and the dependences of the linear viscoelastic functions on the primary molecular weight distribution and the entanglement sites sequence distribution on polymer chain ...
【分类号】
O631
【正文快照】
1 IN’I’RoDUC’I’IoNThe effects of molecular structure fmolecular weight and their distributionl and statedeformation(stress,strain and strain rate)on the chain dynamics of entangled polymerchains have been a subject of intense interest during recent ye