In this paper,we report a new route to syntheses of a series of pure luminescent materials of rare earth phosphates with crystalline phase,microcrystalline glass and glass using microwave method under the condition of appearance microwave power at 20%~70% level(100% power is equal to 650 W of microwave energy, adjusting at 10 level) and reaction time at 7~10 min.The molar ratio of Re2O3 and P2O5 plays an important role for the formation of the luminescent materials of crystalline phase,micro-crystalline g...