In recent years, much attention has been paid on the design, synthesis, crystal structures and properties of the carboxylate complexs, as the carboxylate coordination complexs have fascinating topological structures and various applications in the areas of biology, catalysis, optical and maganetic materials. The design and synthesis of materials with novel structures are topics of current interest and of great challenge. At present, the most chosen carboxylate ligands are rigid aromatic carboxylate.
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