本论文针对目前生物医用材料中的治疗器件、检测器件在使用过程中所面临的生物相容性、功能性差,物理化学稳定性差等难题展开研究,通过化学表面改性技术制备了功能化的聚对二甲苯和碳纳米复合材料。为了赋予聚对二甲苯降解性和功能性,采用化学气相沉积法(CVD)制备了功能型聚对二甲苯共聚物纳米薄膜和纤维,分别研究了其降解性、生物相容性、反应性;同时,为了提高微型器件的导热性能,保证其正常运行,对多壁碳纳米管、纳米石墨微片和石墨烯三种碳系纳米材料进行了改性和制备,并制备了三种不同的碳纳米材料/环氧树脂导热复合材料,研究了碳纳米材料对复合材料导热性能、热稳定性、力学性能的影响。通过CVD方法实现了PCP-N和环状烯酮缩醛BMDO的自由基开环聚合,成功制备了主链可降解的BMDO/PPX-N共聚物纳米薄膜。研究表明,该共聚物薄膜在37°C下碳酸盐缓冲溶液和5 mM KOH/IPA降解液中均可降解,降解过程中,红外谱图中共聚物薄膜中在1784 cm~(-1)处酯键的特征峰逐渐减弱,薄膜在5 mM KOH/IPA中12天内可完全降解,降解一周厚度约减小58.92%;经BMDO改性的PPX-N薄膜表面接触角减小,表面亲水性得到改善;在37...
【英文摘要】
This paper aimed at solving the poor biocompatibility,physical and chemical stability on the treatment and detection device of biomedical materials during the process of application.Functionalized parylene and novel thermal conductive polymer composites were prepared by chemical surface modification.In order to endow parylene with degradation and functionalization,firstly,functionalized parylene copolymer nanofilms and nanofibers were prepared by chemical vapor deposition,respectively.The degradation,biocom...