Solid state NMR can provide unique and important information on the structure of solid catalysts, and the configuration and motion of adsorbates as well as the sequence of reaction steps. Owning to the wealth of structural and dynamical information available via NMR, particularly NMR atomic specificity, high resolution, and quantitative capabilities, solid state NMR method has played an crucial role in the study of the heterogeneous catalysis. In this thesis, the reaction of methanol conversion into hydroca...