Enantioselective epoxidation of olefins is of great importance for the synthesis of a variety of enantiomerically enriched chiral intermediates in fine chemical production such as pharmaceutics, agrochemistry and flavors. There are two general systems for the enantioselective epoxidation of olefins: Sharpless catalytic system and Jacobsen system, effective for the epoxidation of allylic alcohols and nonfunctional alkenes, respectively. In this thesis, two catalytic systems were heterogenized on the surface ...