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熔体过热处理对Cu基块状非晶形成能力的影响及块状非晶的DSC研究

Effect of TRT Process on the Glass Forming Ability of Cu-Based Bulk Amorphous and DSC Study on Bulk Amorphous Alloys

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【作者】 寇生中高忙忙李云飞丁雨田许广济

【Author】 KOU Sheng-zhong1, 2, GAO Mang-mang1, LI Yun-fei1, DING Yu-tian1, XU Guang-ji1(1. State Key Laboratory of Gansu Advanced Non-ferrous Metal Materials, Lanzhou University of Technology, Lanzhou 730050, Gansu, China; 2. Key Laboratory of Non-ferrous Metal Alloys, The Ministry of Education, Lanzhou University of Technology, Lanzhou 730050, Gansu, China)

【机构】 兰州理工大学甘肃省有色金属新材料省部共建国家重点实验室兰州理工大学甘肃省有色金属新材料省部共建国家重点实验室 兰州730050 兰州理工大学有色金属合金省部共建教育部重点实验室兰州730050

【摘要】 在水冷铜坩埚中采用铜模吸铸法制备出直径为3.0mm的Cu50Zr42Al8合金圆棒,研究了熔体过热处理对铜模吸铸法制备块状非晶合金的影响,表明通过熔体过热处理可以提高块状非晶的形成能力,并且存在一个最佳的过热温度。采用DSC技术对铜基成分为Cu50Zr42Al8块状非晶合金进行变温晶化动力学研究,结果表明,随着升温速率的增大,该合金的热稳定性参数和约化玻璃转变温度(Trg)均增大。

【Abstract】 The ternary alloy rods with diameters of 3.0 mm of Cu50Zr42Al8 were prepared by copper mold with suction casting method in water cooling crucible. Effects of TRT(thermal rate treatment)process on bulk amorphous alloys which be prepared by copper mold with suction casting method have been studied. It is found that the GFA(glass forming ability)of the bulk amorphous alloys can be increased by TRT process, and there is a best heating temperature. The kinetics of the non-isothermal crystallization of the Cu50Zr42Al8 by differential scanning calorimeter is studied in the mold of continuous heating. The result indicates that with the increase of the heating rate, the parameter of thermal stability and Trg increase correspondingly.

【基金】 国家自然科学基金(50371016)
  • 【分类号】TG156
  • 【被引频次】9
  • 【下载频次】305
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