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Structure and antibacterial activity of new layered perovskite compounds

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【作者】 谭绍早张力玲夏燎原刘应亮李笃信

【Author】 TAN Shao-zao1, ZHANG Li-ling1, XIA Liao-yuan1, LIU Ying-liang1, LI Du-xin2 1. Department of Chemistry, Ji’nan University, Guangzhou 510632, China; 2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

【机构】 Department of Chemistry Ji’nan UniversityDepartment of Chemistry Ji’nan UniversityState Key Laboratory of Powder Metallurgy Central South UniversityGuangzhou 510632 ChinaChangsha 410083 China

【摘要】 New layered perovskite compounds, AgxNa2-xLa2Ti3O10 (x=0.2, 0.3 and 0.5) were synthesized by an ion-exchange reaction of Na2La2Ti3O10 with AgNO3 solution and characterized by energy dispersive X-ray analysis(EDX), X-ray diffractometry(XRD), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). The ion-exchange processes were optimized, and the antibacterial activity, light permanency and water-resistance were evaluated. Surprisedly, no significant changes in crystal structure of Na2La2Ti3O10 are found by the exchange of silver ions. The Ag0.3Na1.7La2Ti3O10 particles conglomerate obviously with irregular shape and size. Ag0.3Na1.7La2Ti3O10, possessing the minimum inhibitory concentrations(MICs) against Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) of 180 mg/L and 240 mg/L, has high antibacterial activity, good light permanency and water-resistance. The ionic state silver in AgxNa2-xLa2Ti3O10 is the antibacterial active component.

【Abstract】 New layered perovskite compounds, AgxNa2-xLa2Ti3O10 (x=0.2, 0.3 and 0.5) were synthesized by an ion-exchange reaction of Na2La2Ti3O10 with AgNO3 solution and characterized by energy dispersive X-ray analysis(EDX), X-ray diffractometry(XRD), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). The ion-exchange processes were optimized, and the antibacterial activity, light permanency and water-resistance were evaluated. Surprisedly, no significant changes in crystal structure of Na2La2Ti3O10 are found by the exchange of silver ions. The Ag0.3Na1.7La2Ti3O10 particles conglomerate obviously with irregular shape and size. Ag0.3Na1.7La2Ti3O10, possessing the minimum inhibitory concentrations(MICs) against Escherichia coli (E. coli), Staphylococcus aureus (S. aureus) of 180 mg/L and 240 mg/L, has high antibacterial activity, good light permanency and water-resistance. The ionic state silver in AgxNa2-xLa2Ti3O10 is the antibacterial active component.

【基金】 Projects(20676049, 50472077) supported by the National Natural Science Foundation of China;Projects(05200555; 2004B20201026) supported by the Natural Science Foundation of Guangdong Province of China;Project(2005Z3-D212) supported by the Science and Technology Project Fund of Guangzhou City of China
  • 【文献出处】 Transactions of Nonferrous Metals Society of China ,中国有色金属学会会刊(英文版) , 编辑部邮箱 ,2007年02期
  • 【分类号】O611.3
  • 【被引频次】9
  • 【下载频次】71
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