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电沉积NiCoCr-Al2O3泡沫合金及其高温抗氧化性

Electrodeposition of NiCoCr-Al2O3 Foam Alloy and its Antioxidation at High Temperatures

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【作者】 戴高鹏刘素芹朱文杰何亚登

【Author】 DAI Gao-Peng~(a*) LIU Su-Qin~a ZHU Wen-Jie~b HE Ya-Deng~c a Department of Chemistry and Biological Science,Xiangfan University,Xiangfan 441053; b College of Material and Engineer,Central South University,Changsha; c Changsha Lyrun Material Co.,Ltd,Changsha

【机构】 湖北襄樊学院化学与生物科学系中南大学材料与工程学院长沙力元新材料股份有限公司 襄樊 441053襄樊 441053长沙

【摘要】 用电沉积方法制备了NiCoCr-Al2O3泡沫合金,研究了镀液组分对泡沫合金组分的影响。结果表明,随着镀液中CrCl3·6H2O和Al2O3的增加,合金中Cr和Al2O3含量增加,Cr质量分数高于6.8%,镀层变黑, Al2O3质量分数高于8.1%时,合金变脆。合金只有在≥852.37℃热处理后形成了有利于高温抗氧化性的相态,在1 200℃热处理后,合金的高温氧化增重率最低。随着合金中Cr和Al2O3含量的增加,合金的高温抗氧化性提高,且Al2O3含量对高温抗氧化性影响更显著。

【Abstract】 NiCoCr-Al2O3 foam alloy was electrodeposited,the effects of the composition of solution on the properties of foam alloy were studied.The contents of Cr and Al2O3 in the alloy increase with the increases of concentrations of CrCl3·6H2O and Al2O3 in bath,the alloy surface changes to black when Cr in the alloy is over 6.8%;the alloy becomes fragile when Al2O3 in the alloy is over 8.1%.It is foudn that only when the temperature was higher than 852.37℃did the phase which is propitious to antioxidation at high temperatures appear.The effects of treatment temperature on the antioxidation of the alloy at high temperatures were investi- gated,the mass gain was the lowest after the alloy was treated at 1200℃.The effects of chromium and aluminium contents on the antioxidation of the alloy at high temperatures were also studied,the antioxidation of the alloy was improved with increasing the amount of Cr and Al2O3 in the alloy.It is found that Al2O3 promo- ted the antioxidation of the alloy.

  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2007年02期
  • 【分类号】TB383.4
  • 【被引频次】1
  • 【下载频次】118
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