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含锌危险废物的碱法浸出研究

Research on Alkaline Leaching of Hazardous Waste Bearing Zn

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【作者】 张承龙邱媛媛黄希赵由才

【Author】 ZHANG Cheng-long1,2,QIU Yuan-yuan1,HUANG Xi1,ZHAO You-cai1,2(1.The State Key Laboratory of Pollution Control and Resource Reuse,Tongji University,Shanghai 200092,China;2.School of Resource and Environmental Engineering,East China University and Technology,Shanghai 200237,China)

【机构】 同济大学污染控制与资源化研究国家重点实验室同济大学污染控制与资源化研究国家重点实验室 上海200092华东理工大学资源与环境工程学院上海200237上海200092

【摘要】 简述了针对含锌废渣综合利用工艺的现状和不足,提出含锌废渣碱法浸出的新方法,试验得到了较佳工艺:当氢氧化钠浓度为6mol/L、温度为90℃、浸出液固比为10:1时,锌浸出率达91.5%;浸出液体经过净化处理后电沉积可达到《锌粉(GB/T 6890-2000)》一级标准的锌粉,浸出渣中有害元素均低于浸出毒性鉴别标准值(GB5085.3-1996),可作为一般废渣处理,为含锌危险废物的综合利用和处理提供了有效途径。

【Abstract】 In this paper,the present state and shortages of multipurpose utilization of hazardous waste bearing Zn are outlined,and a new method for alkaline leaching of hazardous waste bearing Zn is put forward.A preferable process has been acquired through test: when concentration of NaOH is 6mol/ L,at temperature of 90℃ and ratio of leaching liquid to leaching solid is 10∶1,the leaching rate of Zn obtained is up to 91.5 %;after the leaching solution is purified and then subject to electrowinning,Zn powder in Grade-1 of the Chinese national standard 《Zn Powder(GB/T 6890-2000)》 is obtained.All harmful elements in the leaching residues are under the leaching toxicity identification normal value(GB5085.3-1996),thus are able to be disposed as ordinary waste,which provides an effective approach for multipurpose utilization and disposal of hazardous waste bearing Zn.

  • 【文献出处】 有色冶金设计与研究 ,Nonferrous Metals Engineering & Research , 编辑部邮箱 ,2007年Z1期
  • 【分类号】X705
  • 【被引频次】9
  • 【下载频次】197
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