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氧化酶及烷烃氧化
Oxygenases and Oxygenation of Alkanes
【摘要】 记述了氧化酶在生物催化中的应用.较之传统的化学反应,氧化还原生物催化反应有较好的选择性、可控性和经济性,人们正在积极地寻找这类催化剂.自然界中被高度还原的烃类品种丰富,因此催化烷烃末端或近末端氧合反应的酶也相对容易找到.很多这一类的酶生化特性已作了详细的描述,烷烃加氧酶催化高附加值反应的潜力已得到了广泛地认可.
【Abstract】 This article describes oxidising enzymes used for biocatalytic applications. Redox biocatalysts are highly sought after because of the selectivity, controllability and economy of their reactions, in compari- son with conventional chemical reactions. As highly reduced hydrocarbons are abundant in the environment, enzymes that catalyze the terminal or subterminal oxygenation of alkanes are relatively easy to find. A number of these enzymes have been biochemically characterized in detail, because the potential of alkane hydroxylases to catalyze high added-value reactions was widely recognized.
- 【文献出处】 有机化学 ,Chinese Journal of Organic Chemistry , 编辑部邮箱 ,2007年02期
- 【分类号】O621.25
- 【被引频次】2
- 【下载频次】394