【摘要】 龙脑烯醛是一种重要的精细有机合成中间体,可以用于合成一系列的檀香型香料及其他精细化学品。介绍了以Lewis酸、金属有机骨架和固体酸等作为催化剂由2,3-环氧蒎烷经催化异构制备龙脑烯醛的研究进展,指出以固体酸作为催化剂具有环境友好性,同时在环氧蒎烷催化异构生成龙脑烯醛的反应中具有很好的活性和选择性,具有工业化的潜力和优势。更多还原

【Abstract】 Campholenic aldehyde is an important intermediate in the synthetic aroma chemicals,such as sandalwood fragrances and other fine chemicals.The advances in isomerization of α-pinene oxide to campholenic aldehyde with Lewis acid,metal-organic framework and solid acid as catalysts,are introduced.It is pointed out that solid acids are environmentally beneficial catalysts with high activity and selectivity and have the potential for large-scale application.更多还原