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超声场对碳酸钙反应结晶成核影响的研究(英文)

EFFECT OF ULTRASOUND ON THE NUCLEATION OF CALCIUM CARBONATE DURING REACTIVE CRYSTALLIZATION

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【作者】 杭方学卢群丘泰球姚成灿

【Author】 HANG Fang-xue1,2,LU Qun3,QIU Tai-qiu1,YAO Cheng-can1(1.Light and Chemical Industry Institute,South China University of Technology,Guangzhou 510640,China;2.College of Light Industry and Food Engineering,Guangxi University,Nanning 530004,China;3.Guangdong College of Pharmacy,Guangzhou 510240,China)

【机构】 华南理工大学轻工研究所广东药学院华南理工大学轻工研究所 广东广州510640广西大学轻工与食品工程学院广西南宁530004广东广州510224广东广州510640

【摘要】 研究了超声场作用对反应结晶过程中成核诱导期的影响.以碳酸钙为实验对象,在不同频率和超声作用时间下观察了成核诱导期的变化,结果表明,结晶诱导期随着超声作用时间的增加而缩短.机理分析认为超声场对成核过程的主要影响有两个方面:溶液表面张力的下降和扩散系数的上升.超声场作用可降低成核诱导期.

【Abstract】 The effect of ultrasound on reactive crystallization is studied by measuring the induction time.Calcium carbonate is used as the working substance precipitated by mixing CaCl2 and Na2CO3/NaHCO3 solutions.The experiments were carried with various frequencies and insonation time.It is observed that the induction time significantly decreases with increasing insonation time.The mechanism of the ultrasonic effect on nucleation is analyzed.The two effects of ultrasound are discussed.The surface tension(γ) decreased and the diffusion coefficient(DAB) increased in the ultrasound.The induction time reduced after ultrasound treating.

【关键词】 超声场诱导期结晶成核
【Key words】 ultrasoundinduction timecrystallizationnucleation
【基金】 广东省自然科学基金(980534);广东省重点科技项目(99M02002G)
  • 【文献出处】 陕西科技大学学报(自然科学版) ,Journal of Shaanxi University of Science & Technology , 编辑部邮箱 ,2007年01期
  • 【分类号】O611.3
  • 【被引频次】7
  • 【下载频次】258
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