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静电场作用下H2O偶极极化对冰晶形成过程的影响
Effects of H2O Dipole Polarization on Ice Formation Process Under Electrostatic Field
【摘要】 采用去离子水为实验样品,在-30℃低温环境中冷冻,冷冻过程中施加不同强度的静电场干扰,研究静电场对去离子水冰核形成及冰晶生长过程的影响.研究发现,在冷冻过程初期静电场的引入可以诱发冰核形成,导致过冷点升高,但在随后液相到固相的相变过程中,静电场对冰晶生长具有抑制作用.分析认为,在静电场作用下电偶极矩沿电场方向分布的H2O具有最稳定的状态,能量的分布函数具有最大值,这些结果是诱发冰核形成、抑制冰晶生长的原因.
【Abstract】 The effects of H2O molecules dipole polarization on ice nucleus formation and ice crystal growing under electrostatic field was investigated.De-ionized water,as a sample,was cooled down below-30 ℃,and exposed to different strength electrostatic fields up to 1.0×105 V/m.It was found that at the primary cooling stage,ice nucleus formation could be induced by electrostatic fields to increase H2O supper-cooling temperature.Then during the phase transition from liquid to solid,ice crystal growing was suppressed.The analysis indicates that the H2O whose molecule electrical dipole moment distributing along the direction of electrostatic field gets in the most stable state with the maximum energy distribution function.
【Key words】 electrostatic field; dipole polarization; ice nucleus formation; ice growing;
- 【文献出处】 西安交通大学学报 ,Journal of Xi’an Jiaotong University , 编辑部邮箱 ,2007年02期
- 【分类号】Q6-33
- 【被引频次】20
- 【下载频次】364