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单一手性烯烃铜(Ⅰ)配位聚合物(英文)

A Homochiral Olefin-copper(Ⅰ) Coordination Polymer

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【作者】 庞洁王国喜熊仁根

【Author】 PANG Jie WANG Guo-Xi XIONG Ren-Gen(Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093)

【机构】 南京大学化学化工学院 配位化学研究所配位化学国家重点实验室南京大学化学化工学院配位化学研究所南京210093

【摘要】 The solvothermal reaction of CuCl with R-(-)-1-allyl-3-methylpiperazine at 70 ℃ gives one-dimensional chain Cu-coordination polymer through olefin moiety binding to Cu atoms formulated as Cu(C8H16N2)Cl. It is interesting to note that through Cu2Cl2 dimer unit 1 results in a supramolecular 3-dimensional coordination polymer. Powdered sample measurement of 1 reveals that 1 is second-harmonic generation (SHG) active compound. Crystal parameters for 1, space group P212121, a=0.763 1(9) nm, b=0.891 0(10) nm, c=1.494 6(17) nm, α=90°, β=90°, γ=90°, V=1.016(2) nm3, Z=2, M=478.44, Dc=1.564 Mg·m-3. CCDC: 650193.

【Abstract】 The solvothermal reaction of CuCl with R-(-)-1-allyl-3-methylpiperazine at 70 ℃ gives one-dimensional chain Cu-coordination polymer through olefin moiety binding to Cu atoms formulated as Cu(C8H16N2)Cl. It is interesting to note that through Cu2Cl2 dimer unit 1 results in a supramolecular 3-dimensional coordination polymer. Powdered sample measurement of 1 reveals that 1 is second-harmonic generation (SHG) active compound. Crystal parameters for 1, space group P212121, a=0.763 1(9) nm, b=0.891 0(10) nm, c=1.494 6(17) nm, α=90°, β=90°, γ=90°, V=1.016(2) nm3, Z=2, M=478.44, Dc=1.564 Mg·m-3. CCDC: 650193.

【基金】 国家自然科学基金资助项目(No.NSF20471029)。
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2007年07期
  • 【分类号】O631.3
  • 【被引频次】1
  • 【下载频次】133
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