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牛磺酸缩5-溴水杨醛席夫碱合镍(Ⅱ)配合物的合成及晶体结构
Synthesis, Crystal Structure of a Complex with Nickel(Ⅱ), Taurine 5-bromosalicyladehyde Schiff Base
【摘要】 <正>含C=N结构的金属配合物,以其良好的抗菌、抗癌和抗病毒等广泛的生物活性和药物活性[1 ̄3]及仿酶催化活性[4]而倍受人们的关注。镍是人体必要的痕量元素,在生命过程中起重要的作用。牛磺酸
【Abstract】 The reaction of Ni(Ac)2, Taurine, 5-bromo-salicylaldehyde afford a complex, [Ni(C9H8BrNO4S)(H2O)3]·H2O. Its structure has been determined by single crystal X-ray diffraction. It crystallizes in monoclinic, P21/c, a=1.479 98(6) nm, b=1.397 97(6) nm, c=0.746 60(3) nm, β=99.364(2)°, V=1.524 11(11) nm3. Nickel(Ⅱ) coordinated with six atoms, forming a octahedron. These octahedrons are further interlinked by the hydrogen bonds. CCDC: 639681.
- 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2007年05期
- 【分类号】O641.4
- 【被引频次】10
- 【下载频次】371