节点文献
Synthesis,Characterization and Calorimetry of Ni(C4H8N2O3)2Cl2
【摘要】 A coordination complex was synthesized from NiCl2 and dipeptide glycylglycine(GG). It was characterized by element analysis,NMR and TG methods,and then was determined to be Ni(C4H8N2O3)2Cl2. Using an isoperibolic reaction calorimeter,the standard molar enthalpy of formation of Ni(GG)2Cl2(solid) has been determined to be -(1 674.66±2.02) kJ·mol-1 at 298.15 K.
【Abstract】 A coordination complex was synthesized from NiCl2 and dipeptide glycylglycine(GG). It was characterized by element analysis,NMR and TG methods,and then was determined to be Ni(C4H8N2O3)2Cl2. Using an isoperibolic reaction calorimeter,the standard molar enthalpy of formation of Ni(GG)2Cl2(solid) has been determined to be –(1 674.66±2.02) kJ·mol-1 at 298.15 K.
【Key words】 isoperibolic reaction calorimeter; standard molar enthalpy of formation; coordination complex; glycylglycine; Ni(C4H8N2O3)2Cl2;
- 【文献出处】 Wuhan University Journal of Natural Sciences ,武汉大学自然科学学报(英文版) , 编辑部邮箱 ,2007年03期
- 【分类号】O627.81
- 【下载频次】11