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Synthesis,Characterization and Calorimetry of Ni(C4H8N2O32Cl2

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【Author】 QU Xiaosheng,LI Jie,WANG Zhiyong, WANG Cunxin College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072,Hubei,China

【摘要】 A coordination complex was synthesized from NiCl2 and dipeptide glycylglycine(GG). It was characterized by element analysis,NMR and TG methods,and then was determined to be Ni(C4H8N2O3)2Cl2. Using an isoperibolic reaction calorimeter,the standard molar enthalpy of formation of Ni(GG)2Cl2(solid) has been determined to be -(1 674.66±2.02) kJ·mol-1 at 298.15 K.

【Abstract】 A coordination complex was synthesized from NiCl2 and dipeptide glycylglycine(GG). It was characterized by element analysis,NMR and TG methods,and then was determined to be Ni(C4H8N2O3)2Cl2. Using an isoperibolic reaction calorimeter,the standard molar enthalpy of formation of Ni(GG)2Cl2(solid) has been determined to be –(1 674.66±2.02) kJ·mol-1 at 298.15 K.

【基金】 Supported by the National Natural Science Foundation of China (20373050).
  • 【文献出处】 Wuhan University Journal of Natural Sciences ,武汉大学自然科学学报(英文版) , 编辑部邮箱 ,2007年03期
  • 【分类号】O627.81
  • 【下载频次】11
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