【摘要】 低温条件下,采用水热法,通过控制前驱溶液的pH值,在预先镀有ZnO纳米膜的导电玻璃衬底上制备了形貌各异的ZnO阵列,用X射线衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)和紫外-可见分光光度计等分析手段对ZnO纳米棒的结构和形貌进行了表征．同时还对不同形貌阵列的形成机理进行探讨．结果表明,所制ZnO纳米棒为单晶,沿c轴择优生长．在pH值为10．5左右时,能得到取向性好、直径均匀(d-80nm)的ZnO纳米棒阵列．光学测试表明,在可见光区透光度超过80％,禁带宽度约为3．25eV．更多还原

【Abstract】 By using the hydrothermal method, the ZnO nanorod arrays with different morphologies were synthesized on ZnO nanoparticle-coated transparent conductivity glasses (TCO) at low temperatures by controlling the pH value of precursory solutions. The ZnO nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), high-resolution transmission electron microscope (HRTEM) and ultraviolet-visible spectropho-tometer (UV-Vis). Furthermore, the mechanism was primary discussed. The results show that the ZnO nanorod is a single crystal and it grows along c axis. When the pH value is about 10.5, the array is well-aligned and the diameter of the nanorod is uniform. Optical characterization shows that the optical transmittance of the film is higher than 80% in the visible wavelength and its band gap is about 3.25eV.更多还原