【摘要】 设计并通过4步合成了一种新型的联有邻菲咯啉配位基和发光性能优良的萘基的金属络合物型发光材料化合物(PAN)2Zn,并对其进行了表征.研究表明,最佳的反应条件为:硼酸酯用三异丙基硼酸酯,超声功率为175W,超声时间为15 min,C-C偶合反应的催化剂Pb(OAc)2/P(Ph)3=1∶4(mol),温度为140℃.另外对它的光物理性能进行了初步的研究,结果表明:(PAN)2Zn的最大发射波长为360 nm,并且能够形成激基缔合物,存在明显的溶剂效应,是比较理想的蓝光材料.更多还原

【Abstract】 A novel metal complex,(PAN)2Zn,containing phenanthroline ligand group and naphthalene was synthesized by four steps and characterizied by IR,1 H NMR,EA,MS.The experiment showed that the optimum reaction condition was as follows:using tri(isopropyl)broate,ultrasonic power 175 W,ultrasonic time for 15 min,reaction temperature at 140 ℃ and the C-C coupling reaction catalyst,Pb(OAc)2/P(Ph)3=1∶4(mol).In addition,the photophysical processes(emission spectra,concentration effect and solvent effect) of(PAN)2Zn also were investigated carefully.更多还原