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溶出伏安法测定蔬菜中的铊
Study on Determination of Thallium in Vegetables by Differential Pulse Anodic Stripping Voltammetry
【摘要】 在0.025mol/L醋酸-0.025mol/L醋酸钠缓冲介质中加入EDTA(ethylene diamine tetraacetic acid),以差示脉冲阳极溶出伏安法测定蔬菜中的铊。铊浓度在5.0×10-4~1.0×10-1mg/L范围有良好的线性关系,检出限为1.0×10-4mg/L,回收率为97.0%~104%。对部分蔬菜的测定结果表明,铊污染土壤上种植蔬菜中铊含量显著高于空白土壤上种植的蔬菜。
【Abstract】 The determination of thallium in vegetables by differential pulse anodic stripping voltammetry with 0.025mol/L NaAc-0.025HAc buffer solution with EDTA was studied. The contents of thallium in the range of 5.0×10-4~1.0×10-1mg/L has a good linear relationship and the detection limit is 1.0×10-4mg/L. Using the method to determine some vegetables, the results showed that the thallium contents of vegetables in thallium pollution soil is apparently higher than that in blane soil.
【关键词】 蔬菜;
铊;
差示脉冲阳极溶出伏安法;
测定;
【Key words】 vegetable; thallium; differential pulse anodic stripping voltammetry; determination;
【Key words】 vegetable; thallium; differential pulse anodic stripping voltammetry; determination;
【基金】 国家自然科学基金项目(20477007);中国博士后基金项目(2003034455);广州市属高校科技计划项目(62066);广州联合基金项目(U0633001)
- 【文献出处】 食品科学 ,Food Science , 编辑部邮箱 ,2007年02期
- 【分类号】TS255.7
- 【被引频次】4
- 【下载频次】218