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溶出伏安法测定蔬菜中的铊

Study on Determination of Thallium in Vegetables by Differential Pulse Anodic Stripping Voltammetry

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【作者】 张平姚焱汪珍春陈永亨

【Author】 ZHANG Ping1,YAO Yan2,WANG Zhen-chun2,CHEN Yong-heng1,* (1. Department of Environmental Science, Guangzhou University, Guangzhou 510006, China; 2. Department of Bioengineering, Guangzhou University, Guangzhou 510006, China)

【机构】 广州大学环境科学系广州大学生物工程系广州大学环境科学系 广东广州510006广东广州510006

【摘要】 在0.025mol/L醋酸-0.025mol/L醋酸钠缓冲介质中加入EDTA(ethylene diamine tetraacetic acid),以差示脉冲阳极溶出伏安法测定蔬菜中的铊。铊浓度在5.0×10-4~1.0×10-1mg/L范围有良好的线性关系,检出限为1.0×10-4mg/L,回收率为97.0%~104%。对部分蔬菜的测定结果表明,铊污染土壤上种植蔬菜中铊含量显著高于空白土壤上种植的蔬菜。

【Abstract】 The determination of thallium in vegetables by differential pulse anodic stripping voltammetry with 0.025mol/L NaAc-0.025HAc buffer solution with EDTA was studied. The contents of thallium in the range of 5.0×10-4~1.0×10-1mg/L has a good linear relationship and the detection limit is 1.0×10-4mg/L. Using the method to determine some vegetables, the results showed that the thallium contents of vegetables in thallium pollution soil is apparently higher than that in blane soil.

【基金】 国家自然科学基金项目(20477007);中国博士后基金项目(2003034455);广州市属高校科技计划项目(62066);广州联合基金项目(U0633001)
  • 【分类号】TS255.7
  • 【被引频次】4
  • 【下载频次】218
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