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苎麻织物增强PLA-PCL复合材料的制备及其性能研究

Preparation and Property of PLA-PCL Copolymer Composite Reinforced by Ramie Fabric

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【作者】 刘训堃滕翠青余木火

【Author】 LIU Xun-kun TENG Cui-qing YU Mu-huo (State Key Lab.for Modification of Chemical Fiber & Polymer Material,College of Material Sci.& Eng.,Donghua University,Shanghai 200051,China)

【机构】 东华大学纤维材料国家重点实验室东华大学纤维材料国家重点实验室 上海 200051上海 200051

【摘要】 采用原位聚合法制备了聚乳酸-聚已内酯(PLA-PCL)/苎麻复合材料。研究了硅烷偶联剂(KH550)预处理、纤维含量以及成型工艺对PLA-PCL/苎麻复合材料力学性能的影响。结果表明,经KH550处理后,复合材料的力学性能有不同程度的提高,拉伸强度由49.84MPa到68.95MPa,弯曲强度由34.84MPa提高到65.06MPa,冲击强度由30.13 J/m~2提高到53.54 J/m~2;。在纤维的质量分数为45%,成型温度为170℃,复合材料具有最优性能;采用原位聚合法制备PLA-PCL/苎麻复合材料,复合材料的界面性能较好。

【Abstract】 PLA-PCL/ramie fabric composite was prepared by means of in-situ polymerization.The effects of the pretreatment of ramie fabric with silane coupling agent,the content of the fiber and molding conditions on the mechanical properties of PLA-PCL/ramie fabric laminate were studied.The results showed after the treatment by the coupling agent KH550,the mechanical properties of the composite were improved to a certain extent,among which tensile strength increased from 49.84 MPa to 68.95 MPa,bending strength increased from 34.84 MPa to 65.06 MPa,impact strength increased from 30.13 J/m~2 to 53.54 J/m~2;when the mass fraction of the fabric was 45% and molded at 170℃,the mechanical properties of the composite were the best,and the composite prepared by means of in-situ polymerization had better interfacial property.

【基金】 国家自然科学基金(50573010、20504006)
  • 【文献出处】 塑料工业 ,China Plastics Industry , 编辑部邮箱 ,2007年01期
  • 【分类号】TQ327
  • 【被引频次】36
  • 【下载频次】677
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