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氧气的体积分数对N2O热分解的影响

Influence of oxygen concentration on thermal decomposition of N2O

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【作者】 侯祥松张海岳光溪

【Author】 HOU Xiang-song,ZHANG Hai,YUE Guang-xi(Department of Thermal Engineering,Key Laboratory for Thermal Science and Power Engineering of Ministry of Education,Tsinghua University,Beijing 100084,China)

【机构】 清华大学热能工程系热科学与动力工程教育部重点实验室清华大学热能工程系热科学与动力工程教育部重点实验室 北京100084北京100084

【Abstract】 Thermal decomposition is an effective method to reduce N2O concentration in flue gas.The experiment was conducted with a fix bed reactor.The N2O concentrations before and after reactor under different O2 concentrations were measured and compared.The results show that the increase of oxygen concentration slows the reaction speed of thermal decomposition of N2O.The influence mechanism of oxygen concentration on the thermal decomposition of N2O is simulated with P.Glarborg’s model.The increase of oxygen will reduce the concentrations of H and OH which mainly decide the reaction speed of thermal decomposition of N2O.It is necessary to control the oxygen concentration to increase the de-N2O efficiency by thermal decomposition.

【关键词】 N2O热分解氧气Chemkin
【Key words】 N2Othermal decompositionoxygenChemkin
【基金】 国家重点基础研究发展规划(973计划,2006CB200301)
  • 【文献出处】 燃料化学学报 ,Journal of Fuel Chemistry and Technology , 编辑部邮箱 ,2007年04期
  • 【分类号】X701
  • 【被引频次】6
  • 【下载频次】264
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