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CVD法制备微螺旋炭纤维的研究

Synthesis of Micro-coiled Carbon Fibers by CVD

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【作者】 毕辉寇开昌张教强陈碧波

【Author】 BI Hui,KOU Kai-chang,ZHANG Jiao-qiang,CHEN Bi-bo (Department of Applied Chemistry,School of Science,Northwestern Polytechnical University,Xi’an 710072,China)

【机构】 西北工业大学理学院应用化学系西北工业大学理学院应用化学系 西安710072西安710072

【摘要】 以乙炔为碳源,Ni粉为催化剂,含硫化合物噻吩为助催化剂,通过化学气相沉积法(CVD)制得了微螺旋炭纤维。利用扫描电子显微镜(SEM)考察了微螺旋纤维的微观形貌,发现所得的纤维几乎为双螺旋,同时通过对影响微螺旋炭纤维生长因素研究,发现有利于微螺旋炭纤维生长的最佳反应条件:反应温度为750℃,噻吩温度为30℃,H2/C2H2=3,反应时间为2h,石墨棒竖直起来放置。

【Abstract】 Micro-coiled carbon fibers were prepared by chemical vapor deposition method,using acetylene as the carbon source,a nickel powder as catalyst and thiophene as impurity.The microstructures of the carbon micro-coils were examined by SEM.It was found that most of micro-coiled carbon fibers were double helical forms.Reaction conditions which affected the growth of carbon micro-coils were investigated.The optimum reaction conditions for carbon micro-coils formation were as follows:reaction temperature 750℃,H2/C2H2=3,the thiophene temperature 30℃,reaction time 2h,graphite block setting vertically in the centre of quartz tube,which is propitious to grow micro-coiled carbon fibers

【基金】 陕西省自然科学基金(No.N6CS0005);西北工业大学研究生创新基金(No.06043)资助项目
  • 【文献出处】 人工晶体学报 ,Journal of Synthetic Crystals , 编辑部邮箱 ,2007年03期
  • 【分类号】TM242
  • 【被引频次】10
  • 【下载频次】140
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