【摘要】 以1,10-邻菲咯啉为配体,合成了标题配合物,该化合物的分子式Cu2+(phen)(SCN-)2,分子量359.90,采用经单色化的Mo ka(λ=0.71073)射线测定,共收集3850个衍射点,其中独立衍射点1555个,[Ι>2ó(I)]可观测点数1233个。结果表明该化合物属单斜晶系,C2/c空间群,其晶胞参数:a=1.4067(3)nm,b=1.03281(18)nm,c=1.02975(18)nm,β=111.104(2)o,V=1.3957(4)nm3,z=4,Dc=1.713g.cm-3,μ=1.859 mm-1,F(000)=724,s=1.024,(Δρ)max=0.307e-3和(Δρ)m in=-0.305e-3。该配合物是四配位的平面四边形结构。更多还原

【Abstract】 The reaction of transition metal with 1,10-phenanthroline base gave the title complex Cu(2+)(phen)(SCN-)2 [phen= 1,10-phenanthroline,SCN-=silver thiocyanate],and its crystal structure was determined by x-ray diffraction.The complex crystallizes in monoclinic,space group C2/c with a=1.4067(3)nm,b=1.03281(18)nm,c=1.02975(18) nm β=111.104(2),V=1.3957(4)nm3,z=4,Dc=1.713g.cm(-3),μ=1.859 mm(-1),F(000)=724,s=1.024,(Δρ)max= 0.307 和(Δρ)min =-0.305e(-3).In the complex,the Cu(Ⅱ) atom is four-coordinated to assume a plane quadrilateral geometry.更多还原