【摘要】 以马来酸酐和环己醇为原料,无水AlCl3为异构化剂,合成了富马酸单环己酯(MCHF)。讨论了酯化温度、异构化剂、异构化温度和异构化时间对反应产物的影响。结果表明:MCHF产率为73.8%,气相色谱分析纯度达98%以上。经质谱(MS)和核磁共振(NMR)等现代仪器分析,确定了MCHF的结构。更多还原

【Abstract】 Using maleic anhydride and cyclohexanol as raw material and anhydrous aluminum trichloride as isomerizing agent,mono-cyclohexyl fumarate was synthesized.Efflects of esterification temperature、isomerizing agent、isomerizing temperature and isomerizing time on reaction were discussed.The result showed that under the best conditions,the yield was about 73.8 %,the purity was above 98 %.at last, the structure of mono-cyclohexyl fumarate was characterized by MS and NMR.更多还原