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用表面活性剂合成磷酸铝介孔分子筛

Sythesis of Aluminophosphate Mesostructured Molecular Sieve by Surfactants

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【作者】 吕彤姜炜杜开封吴赞敏

【Author】 LV Tong1,JIANG Wei2,DU Kai-feng1,WU Zan-min1(1.School of Material Science and Chemical Engineering,Tianjin Polytechnic Uninersity,Tianjin 300160,China;2.Department of Chemistry,Tianjin Medical University,Tianjin 300070,China)

【机构】 天津工业大学材料化工学院天津医科大学基础医学院化学系天津工业大学材料化工学院 天津300160天津300070天津300160

【摘要】 选用了不同类型的表面活性剂作为模板剂合成磷酸铝介孔分子筛,实验结果表明,脂肪胺模板剂的浓度不会影响分子筛介孔相构型,介孔分子筛的孔径随烷基胺的链长增加而增大,其比表面积均达到了200m2/g以上.类型相同的表面活性剂作模板剂时,分子筛的孔径和比表面积并不随其浓度增加而增加.所合成的磷酸铝分子筛TG和°DTA曲线表明,磷酸铝分子筛在850℃以前具有一定的热稳定性.

【Abstract】 Differente types of the surfactant are selected as template synthesized mesostructured aluminophosphate.The test result shows that aliphatic amine concentration of template does not l not affect the mesostructured phase configuration,and the pore diameter of molecular sieve increases with the growth of clain lengt and both specific areas reach more than 200 m2/g.When the same type of surfactant is used as the template,the pore diameter of molecular sieve and specific area do not increase along with its concentration rise.The TG and DTA of synthetic mesostructured aluminophosphate shows that there is heat stabilization under 850℃.

  • 【文献出处】 昆明理工大学学报(理工版) ,Journal of Kunming University of Science and Technology(Science and Technology) , 编辑部邮箱 ,2007年01期
  • 【分类号】TQ424.25
  • 【被引频次】3
  • 【下载频次】303
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