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氨基磺酸盐系高效减水剂的改性研究

Study on Modification of Amino-sulfonic Acid-based Water-reducer

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【作者】 张智强; 钱中秋; 饶枭宇; 丁虹;

【Author】 ZHANG Zi-qiang 1,QIAN Zhong-qiu 1,2,RAO Xiao-yu 1,DING Hong 3(1.College of Materials Science and Engineering,Chongqing University,Chongqing 400045,China;2.Changzhou Construction Research Institute Co.Ltd,Changzhou 213015,China;3.College of Architecture and Civil Engineering,Xihua University,Chengdu 610039,China)

【机构】 重庆大学材料科学与工程学院; 西华大学建筑与土木工程学院 重庆400045; 重庆400045; 常州市建筑科学研究院有限公司; 江苏常州213015; 四川成都610039;

【摘要】 氨基磺酸盐系减水剂具有高减水率、抑制混凝土塌落度经时损失等优点,但泌水严重,限制了其在混凝土中的应用。本文根据“分子设计”原则,通过单体A和单体U引入适当的官能团,对传统氨基磺酸盐系高效减水剂进行改性,测试了产品对水泥净浆流动度、流动度经时损失和泌水率的影响。试验表明,单体A的改性效果优于单体U,以9%的单体A改性后,减水剂的分散性和分散保持性能好,泌水率显著降低。

【Abstract】 Amino-sulfonic acid-based water-reducer is characterized by high water-reducing rate and restraining the concrete mixture from slump loss with time.The application of amino-sulfonic acid-based water-reducer in concrete mixture was restricted due to its high bleeding.Based on principles of molecular design,the traditional superplasticizer of aminosulfonic acid series was modified by the suitable functional group introduced by monomer A and monomer U.The effects of such product on the fluidity,fluidity loss with time and bleeding rate of cement paste were tested.It was found that the modifying effect of monomer A for the superplasticizer was better than that of monomer U.The dispensability and flow retainability of superplasticizer were strong and the bleeding rate of cement paste added with superplasticizer modified by 9% monomer A was reduced obviously.

  • 【文献出处】 重庆建筑大学学报 ,Journal of Chongqing Jianzhu University , 编辑部邮箱 ,2007年02期
  • 【分类号】TU528.042.2
  • 【被引频次】13
  • 【下载频次】274
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