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Syntheses of CuO nanostructures in ionic liquids

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【Author】 WANG Li,ZHAO Bin,YUAN ZhongYong,ZHANG XueJun,Wu QingDuan,CHANG LiXian &ZHENG WenJun College of Chemistry,Nankai University,Tianjin 300071,China

【摘要】 A simple and efficient approach is developed to fabricate single-crystalline CuO nanostructures through an ionic liquid assisted one-step low-temperature solid-state route.Both nanoparticles(5 nm in size)and nanorods(5-10 nm in diameter and 50-100 nm in length)of monoclinic CuO were obtained. These synthesized CuO nanostructures were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),selected area electron diffraction(SAED),X-ray photoelectron spectros- copy(XPS),energy dispersive spectroscopy(EDS)and nitrogen adsorption analysis.The morpholo- gies of the nanostructures can be controlled by tuning the amount of NaOH and ionic liquids.The growth mechanism of CuO nanostructures is investigated.

【Abstract】 A simple and efficient approach is developed to fabricate single-crystalline CuO nanostructures through an ionic liquid assisted one-step low-temperature solid-state route.Both nanoparticles(5 nm in size)and nanorods(5-10 nm in diameter and 50-100 nm in length)of monoclinic CuO were obtained. These synthesized CuO nanostructures were characterized by X-ray diffraction(XRD),transmission electron microscopy(TEM),selected area electron diffraction(SAED),X-ray photoelectron spectros- copy(XPS),energy dispersive spectroscopy(EDS)and nitrogen adsorption analysis.The morpholo- gies of the nanostructures can be controlled by tuning the amount of NaOH and ionic liquids.The growth mechanism of CuO nanostructures is investigated.

【基金】 the National Natural Science Foundation of China(Grant Nos.20273033 and 20571044);the National Basic Research Program of China(973Program)(Grant No.2005CB623607)
  • 【文献出处】 Science in China(Series B:Chemistry) ,中国科学(B辑:化学)(英文版) , 编辑部邮箱 ,2007年01期
  • 【分类号】O614.121
  • 【被引频次】6
  • 【下载频次】64
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