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Ni[S2P（OCH2CH2Ph）2]2·2Py的制备及结构表征
Synthesis and structure characterizetion of adduct Ni[S2P（OCH2CH2Ph）2]2·2Py
【Abstract】 The adductive reaction of Ni[S2P(OCH2CH2Ph)2]2 with pyridine was studied by spectrographic method and the equilibrium constants was found to be β1=(1.12±0.09)×102,β2=(2.40±0.41)×104,R1=0.997,R2=0.998.The adduct Ni[S2P(OCH2CH2Ph)2]2·2Py was characterized by elemental analysis,IR spectra,single-crystal X-ray diffraction method.The crystal structure belongs to monoclinic system,space group P 21/c with the following crystallographic parameters:a=9.240(3),b=16.124(8),c=14.148(7),α=90.00°,β=92.07(4)°,γ=90.00°.
【基金】 四川省教育厅自然科学基金预研项目(2005C016)资助;自贡市科技局项目(06G2045)资助
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2007年05期
- 【分类号】O627.81
- 【被引频次】8
- 【下载频次】56