【Abstract】 Poly(o-pheneylidiamine) was synthesized by using facial synthesis method.The FTIR spectra,UV-vis absorption spectra and X-ray diffraction patterns were used to characterize the molecular structures of the polymer.The morphologies of powders were studied by using TEM.Voltammetric study was done to investigate the electrochemical behaviors of poly(o-pheneylidiamine).The structure,crystallinity,morphology and electrochemical activity of the polymer were discussed.The results showed that Poly(o-pheneylidiamine) particles appeared as micro sticks in the micrograph,their diameter is from several decade nanometers to more than 100 nanometers.X-ray diffraction patterns showed the poly(o-pheneylidiamine) was highly ordered and put up a crystalloid form of suppositional simple cubic crystal.Voltammetric study indicated that the poly(o-pheneylidiamine) synthesized by facial synthesis method had good electrochemical activity.更多还原