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掺杂PbO2/Ti阳极在硫酸铬电氧化过程的电极行为

Behavior of doped PbO2/Ti anode in electrooxidation of chromium sulfate

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【作者】 王留成李晓乐赵建宏宋成盈徐海升

【Author】 WANG Liu-cheng*,LI Xiao-le,ZHAO Jian-hong,SONG Cheng-ying,XU Hai-sheng(College of Chemical Engineering,Zhengzhou University,Zhengzhou 450002,China)

【机构】 郑州大学化工学院郑州大学化工学院 河南郑州450002河南郑州450002

【Abstract】 Electrodeposited PbO2/Ti doped with Bi,Ce,Cu or Sn with an intermediate layer was prepared.The electrochemical parameters in the oxidation process of Cr2(SO4)3 were determined by steady-state polarization curve.The current efficiency of Bi-doped,Ce-doped,Cu-doped,Sn-doped and undoped PbO2/Ti in the preparation of dichromic acid by electrooxidation of chromium sulfate were investigated.The result showed Ce-doped PbO2/Ti exhibited the best electrocatalytic activity in the undoped and doped PbO2/Ti mentioned above.

【关键词】 二氧化铅电极硫酸铬电氧化
【Key words】 PbO2 anodechromium sulfateelectrooxidation
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2007年02期
  • 【分类号】O646.54
  • 【被引频次】17
  • 【下载频次】192
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