节点文献

四-α-(2-甲基-8-喹啉氧基)酞菁金属配合物的合成、表征及光敏活性研究

Synthesis,Characterization and Photosensitivity Study of Tetrakis-α-(2-methyl-8-quinolinoxy)metallophthalocyanines

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 XUE,Jin-Pinga LIU,Honga FAN,Chang-Anb HONG,Hu-Mingc CHEN,Nai-Sheng,a HUANG,Jin-Linga(a Institute of Functional Materials,College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou 350002)(b Fujian Sanming Jianning Fire Company,Sanming 354500)(c Laboratory of Physics and Chemistry,Taigu Aeroengineering Ltd.,Xiamen 361006)

【机构】福州大学化学化工学院功能材料研究所；福建省三明市建宁消防大队；厦门太古飞机工程有限公司理化实验室；福州大学化学化工学院功能材料研究所福州350002；福州350002；三明354500；厦门361006；

【摘要】利用DBU催化法合成得到4种两亲性的四-α-(2-甲基-8-喹啉氧基)酞菁金属配合物[金属=Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ),Zn(Ⅱ)],同时分别进行了元素分析、质谱、UV-Vis、IR光谱表征.测定了它们在670nm光激发下产生单线态氧的速率及光动力氧化氨基酸底物的速率常数,探讨了它们光敏活性的构效关系.更多还原

【Abstract】 Cobalt(Ⅱ),nickel(Ⅱ),copper(Ⅱ)and zinc(Ⅱ)coordination compounds of tetrakis-α-(2-methyl-8-quinolinoxy)phthalocyanine were synthesized by means of "DBU method".The title complexes were char-acterized by elemental analysis,mass spectrum,UV-Vis and IR spectra.In addition,the rates of photo-generating singlet oxygen and the rate constants of photodynamic oxidation of amino-acid for the complexes were measured by irradiation of laser at 670 nm,and the relations between their structures and photosensitivities were discussed.更多还原

【关键词】 2-甲基-8-喹啉氧基；酞菁金属配合物；合成；表征；光敏活性；
【Key words】 2-methyl-8-quinolinoxy； metallophthalocaynine； synthesis； characterization； photosensitivity；

【基金】福建省科技厅国际合作项目(No.2003I018);福建省科技厅重点(No.2006Y0020)资助项目.

【文献出处】化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2007年16期

【分类号】O641.4
【被引频次】16
【下载频次】262

知网节下载

节点文献中：

本文链接的文献网络图示:

本文的引文网络

节点文献